Elucidating the mechanism of the CO2 methanation reaction over Ni–Fe hydrotalcite-derived catalysts via surface-sensitive in situ XPS and NEXAFS

Author:

Giorgianni Gianfranco123ORCID,Mebrahtu Chalachew4567ORCID,Schuster Manfred Erwin8910ORCID,Large Alexander Ian1112910,Held Georg111291013ORCID,Ferrer Pilar13141510ORCID,Venturini Federica13141510,Grinter David13141510ORCID,Palkovits Regina4567ORCID,Perathoner Siglinda1617181920ORCID,Centi Gabriele212223203ORCID,Abate Salvatore1617181920ORCID,Arrigo Rosa1314151024ORCID

Affiliation:

1. University of Calabria

2. I-87036 Rende (CS)

3. Italy

4. Institute for Technical and Macromolecular Chemistry (ITMC)

5. RWTH Aachen University

6. Aachen

7. Germany

8. Johnson Matthey Technology Centre

9. Reading

10. UK

11. Department of Chemistry

12. University of Reading

13. Diamond Light Source

14. Harwell Science and Innovation Campus

15. Didcot

16. Dipartimento di Scienze Chimiche

17. Biologiche

18. Farmaceutiche ed Ambientali-ChiBioFarAm

19. viale Ferdinando Stagno D'Alcontres

20. 98166 Messina

21. Dept. MIFT (Industrial Chemistry)

22. University of Messina

23. ERIC aisbl and INSTM/CASPE V.le F. Stagno D’Alcontres 31

24. School of Science

Abstract

In situ surface sensitive XPS and NEXAFS clarify the promotion effect of Fe in Ni–Fe/hydrotalcite-derived catalysts for the CO2 methanation reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference38 articles.

1. International Energy Outlook 2019, Washington, DC 20585 U.S., 2019, https://www.eia.gov/outlooks/ieo/pdf/ieo2019.pdf , accessed on 30 September 2019

2. Intermittent Renewable Energy Sources: The Role of Energy Storage in the European Power System of 2040

3. P. Ralon , M.Taylor and A.Ilas , Electricity storage and renewables: Costs and markets to 2030, https://www.irena.org/publications/2017/Oct/Electricity-storage-and-renewables-costs-and-markets , accessed 30 September 2019

4. Electrical energy storage systems: A comparative life cycle cost analysis

5. Renewable Power-to-Gas: A technological and economic review

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