A short, versatile chemical synthesis of l- and d-amino acids stereoselectively labelled solely in the beta position
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2005/OB/B508196C
Reference12 articles.
1. Versatile synthesis of stereospecifically labelledD-amino acids via labelled aziridines—preparation of (2R,3S)-[3-2H1]- and (2R,3R)-[2,3-2H2]-serine; (2S,2′S,3S,3′S)-[3,3′-2H2]- and (2S,2′S,3R,3′R)-[2,2′,3,3′-2H4]-cystine; and (2S,3S)-[3-2H1-] and (2S,3R)-[2,3-2H2]-β-chloroalanine
2. Versatile synthesis of L-α-amino acids stereospecifically labelled on the β-carbon atom
3. Synthesis of the suicide substrate D-propargylglycine stereospecifically labelled with deuterium and investigation of its oxidation by D-amino acid oxidase 1
4. Stereochemistry of conversion of the suicide substrates β-chloro-D-alanine-andD- andL-serine O-sulfates into pyruvate byD-amino acid aminotransferase and byL-aspartate aminotransferase
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