Single metal four-electron reduction by U(ii) and masked “U(ii)” compounds
Author:
Affiliation:
1. Institut des Sciences et Ingénierie Chimiques
2. Ecole Polytechnique Fédérale de Lausanne (EPFL)
3. Lausanne
4. Switzerland
5. LPCNO
6. Université de Toulouse
7. INSA Toulouse
8. Toulouse
9. France
Abstract
Both a masked and the actual complex [U(ii){N(SiMe3)2}3]+ effect the reduction of azobenzene to yield a U(vi) bis-imido species providing the first example of a “clear-cut” metal centred four-electron reduction in f-element chemistry.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00668A
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