Electronic characterization of redox (non)-innocent Fe2S2 reference systems: a multi K-edge X-ray spectroscopic study
Author:
Affiliation:
1. Sustainable Materials Characterization
2. Van't Hoff Institute for Molecular Sciences
3. University of Amsterdam
4. 1098 XH Amsterdam
5. The Netherlands
6. Materials Chemistry
7. Zernike Institute for Advanced Materials
8. 9747AG Groningen
Abstract
Di-iron dithiolate hydrogenase model complexes are promising systems for electrocatalytic production of dihydrogen and have therefore been spectroscopically and theoretically investigated in this study.
Funder
Nederlandse Organisatie voor Wetenschappelijk Onderzoek
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/RA/C9RA08903A
Reference42 articles.
1. How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study
2. Radical‐Type Reactivity and Catalysis by Single‐Electron Transfer to or from Redox‐Active Ligands
3. The Shrinking World of Innocent Ligands: Conventionaland Non‐Conventional Redox‐Active Ligands
4. Spectroscopic and theoretical investigation of the [Fe2(bdt)(CO)6] hydrogenase mimic and some catalyst intermediates
5. Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex
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