Remote p–d orbital hybridization <i>via</i> first/second-layer coordination of Fe single atoms with heteroatoms for enhanced electrochemical CO<sub>2</sub>-to-CO reduction-Reference-Cited by-同舟云学术

Remote p–d orbital hybridization via first/second-layer coordination of Fe single atoms with heteroatoms for enhanced electrochemical CO₂-to-CO reduction

Published:2024 Issue:15 Volume:12 Page:8991-9001
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Yang Ying¹,Chen Lizhen²,Guo Zhenyan¹,Liu Shengqi¹,Wu Pei-dong¹³,Fang Zhen³^ORCID,Zhang Kai²^ORCID,Li Hu¹^ORCID

Affiliation:

1. National Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide & Agricultural Bioengineering, Ministry of Education, State-Local Joint Laboratory for Comprehensive Utilization of Biomass, Center for R&D of Fine Chemicals, Guizhou University, Guiyang 550025, China

2. Department of Wood Technology and Wood-based Composites, University of Göttingen, D-37077 Göttingen, Germany

3. Biomass Group, College of Engineering, Nanjing Agricultural University, 40 Dianjiangtai Road, Nanjing, Jiangsu 210031, China

Abstract

d–p orbital hybridization induced by S/N in the coordination layer of pyrrole-type Fe–N4 can modulate the electronic structure of Fe single atoms, enabling *COOH adsorption and *CO desorption to exclusively furnish CO but suppressing H2 formation.

Funder

National Natural Science Foundation of China

Science and Technology Program of Guizhou Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA08021H

Reference74 articles.

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4. Porosity-Induced High Selectivity for CO2 Electroreduction to CO on Fe-Doped ZIF-Derived Carbon Catalysts

5. Synergistic electrocatalysis of crystal facet and O-vacancy for enhancive urea synthesis from nitrate and CO2

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