Hydrazine-mediated strongly coupled Re(CO)3 dimers-Reference-Cited by-同舟云学术

Hydrazine-mediated strongly coupled Re(CO)3 dimers

Published:2015 Issue:39 Volume:44 Page:17268-17277
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hasheminasab A.¹²³,Rhoda H. M.⁴⁵⁶³,Crandall L. A.¹²³,Ayers J. T.¹⁷⁸³,Nemykin V. N.⁴⁵⁶³,Herrick R. S.¹⁷⁸³,Ziegler C. J.¹²³

Affiliation:

1. Department of Chemistry

2. University of Akron

3. USA

4. Department of Chemistry & Biochemistry

5. University of Minnesota Duluth

6. Duluth

7. College of the Holy Cross

8. Worcester

Abstract

We present two strongly coupled Re(CO)₃ dimers, where the metals are linked via a bis-hydrazine Schiff base ligand as well as their monomeric analogs. Strong coupling between the ligand based orbitals the dimers is observed as measured by reductive cyclic voltammetry.

Funder

American Chemical Society Petroleum Research Fund

Directorate for Biological Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02821C

Reference59 articles.

1. Synthesis and photophysical and electrochemical properties of new halotricarbonyl(polypyridine)rhenium(I) complexes

2. Phosphorescent Organic Light-Emitting Diodes with Outstanding External Quantum Efficiency using Dinuclear Rhenium Complexes as Dopants