Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P–N bond activation, a transient phosphaallene, a zwitterionic AlP2C2heterocycle and a masked Al/P-based frustrated Lewis pair-Reference-Cited by-同舟云学术

Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P–N bond activation, a transient phosphaallene, a zwitterionic AlP2C2heterocycle and a masked Al/P-based frustrated Lewis pair

Published:2016 Issue:5 Volume:45 Page:2031-2043
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Klöcker Hans¹²³,Layh Marcus¹²³,Hepp Alexander¹²³,Uhl Werner¹²³

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Universität Münster

2. D-48149 Münster

3. Germany

Abstract

Hydroalumination of alkynyl-aminophosphines afforded an AlP₂C₂heterocycleviaP–N bond activation and a transient phosphaallene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02825F

Reference61 articles.

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2. STRUCTURES OF PHOSPHAETHYLENES AND A 1-PHOSPHAALLENE CONTAINING PHOSPHORUS IN LOWER COORDINATION STATE

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4. Heavy Allenes and Cumulenes ECE‘ and ECCE‘ (E = P, As, Si, Ge, Sn; E‘ = C, N, P, As, O, S)

5. Group 14 and 15 Heteroallenes ECC and ECE‘

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