Reaction of a polydentate cysteine-based ligand and its nickel(ii) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity-Reference-Cited by-同舟云学术

Reaction of a polydentate cysteine-based ligand and its nickel(ii) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity

Published:2015 Issue:42 Volume:44 Page:18378-18385
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Warner D. S.¹²³⁴,Limberg C.¹²³⁴,Oldenburg F. J.¹²³⁴,Braun B.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Humboldt-Universität zu Berlin

3. 12489 Berlin

4. Germany

Abstract

A cysteine-based nickel(ii) complex reacts with methylating reagents followed by CO treatment via acetylation of the thiolate function corresponding to the ACS reactivity.

Funder

BASF Corporation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02828K

Reference62 articles.

1. Ni-Zn-[Fe4-S4] and Ni-Ni-[Fe4-S4] clusters in closed and open α subunits of acetyl-CoA synthase/carbon monoxide dehydrogenase

2. Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas