Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support-Reference-Cited by-同舟云学术

Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support

Published:2018 Issue:38 Volume:47 Page:13550-13558
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Palermo Andrew P.¹²³⁴⁵^ORCID,Zhang Shengjie⁶⁷⁸⁴,Hwang Son-Jong⁹¹⁰¹¹⁴^ORCID,Dixon David A.⁶⁷⁸⁴^ORCID,Gates Bruce C.¹²³⁴^ORCID,Katz Alexander⁵²¹²⁴^ORCID

Affiliation:

1. Department of Chemical Engineering

2. University of California

3. Davis

4. USA

5. Department of Chemical and Biomolecular Engineering

6. Department of Chemistry

7. The University of Alabama

8. Tuscaloosa

9. Division of Chemistry and Chemical Engineering

10. California Institute of Technology

11. Pasadena

12. Berkeley

Abstract

A substituted tetrairidium carbonyl cluster on a silica support undergoes hydrogen activation at a rate and with a mechanism different from the cluster in solution.

Funder

Basic Energy Sciences

National Science Foundation

University of Alabama

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01371C

Reference25 articles.

1. Intrazeolite chemistry of nickel(0) complexes and Ni(0,II) clusters studied by EXAFS, solid-state NMR and FT-IR spectroscopy