A BF3-mediated C–H/C–Li coupling of 1,3,7-triazapyrene with 2-thienyllithium in the design of push–pull fluorophores and chemosensors for nitroaromatics

Author:

Lavrinchenko Igor A.1,Moseev Timofey D.1ORCID,Varaksin Mikhail V.12ORCID,Zyryanov Grigoriy V.12,Taniya Olga S.1,Tsmokalyuk Anton N.1,Demidov Oleg P.3,Borovlev Ivan V.3,Charushin Valery N.12,Chupakhin Oleg N.12ORCID

Affiliation:

1. Ural Federal University, 19 Mira Str., 620002 Ekaterinburg, Russia

2. Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Str., 620990 Ekaterinburg, Russia

3. North Caucasus Federal University, 355009, Stavropol, Russia

Abstract

A BF3-mediated strategy of oxidative nucleophilic substitution of hydrogen affords mono- and bis-substituted thiophene-derived 1,3,7-triazapyrene fluorophores of interest in the design of luminescent materials and chemosensors for nitroaromatics.

Funder

Council on grants of the President of the Russian Federation

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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