Radical-initiated P,P-metathesis reactions of diphosphanes: evidence from experimental and computational studies
Author:
Affiliation:
1. School of Chemistry
2. University of Bristol
3. Bristol BS8 1TS
4. UK
5. Chemistry Research Laboratory
6. University of Oxford
7. Oxford OX1 3TA
8. Cardiff Catalysis Institute
9. Cardiff University
10. Cardiff CF10 3AT
Abstract
The mechanism by which P,P-exchange reactions can occur rapidly under ambient conditions has been investigated and the experimental evidence, combined with computational studies, support a radical process.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01013A
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