Molecular mechanism comparison of decarbonylation with deoxygenation and hydrogenation of 5-hydroxymethylfurfural catalyzed by palladium acetate-Reference-Cited by-同舟云学术

Molecular mechanism comparison of decarbonylation with deoxygenation and hydrogenation of 5-hydroxymethylfurfural catalyzed by palladium acetate

Published:2019 Issue:7 Volume:21 Page:3795-3804
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Xie Hong¹²³⁴^ORCID,Qi Ting¹²³⁴^ORCID,Lyu Ya-Jing⁵⁶⁷²³^ORCID,Zhang Jin-Feng¹²³⁴^ORCID,Si Zhen-Bing¹²³⁴^ORCID,Liu Li-Juan¹²³⁴^ORCID,Zhu Liang-Fang⁵⁶⁷²³^ORCID,Yang Hua-Qing¹²³⁴^ORCID,Hu Chang-Wei⁵⁶⁷²³^ORCID

Affiliation:

1. College of Chemical Engineering

2. Sichuan University

3. Chengdu

4. P. R. China

5. Key Laboratory of Green Chemistry and Technology

6. Ministry of Education

7. College of Chemistry

Abstract

For HMF, decarbonylation goes through the metal-acetate-co-assisted deprotonation mechanism, while both deoxygenation and hydrogenation proceed via the oxidative addition mechanism.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP07723A

Reference53 articles.

1. Conversion of biomass to selected chemical products

2. Catalytic conversion of 5-hydroxymethylfurfural to some value-added derivatives

3. Highly Selective Decarbonylation of 5-(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide