Regioselective Diels–Alder reaction to open-cage ketolactam derivatives of C60

Author:

Tanaka Teruhiko12345,Nojiri Ryuichi12345,Sugiyama Yoshiki12345,Sawai Ryouhei12345,Takahashi Toshikazu675,Fukaya Norihisa675ORCID,Choi Jun-Chul675ORCID,Kabe Yoshio12345ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Kanagawa University

4. Hiratsuka 259-1293

5. Japan

6. National Institute of Advanced Industrial Science and Technology (AIST)

7. Tsukuba

Abstract

Open-cage ketolactam fullerenes reacted with dienes on the rim of the orifice both regio- and endo-selectively, which were confirmed by 2D INADEQUATE 13C NMR of 13C enriched material/HMBC spectra as well as the theoretical calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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