The electron that breaks the catalyst's back – excited state dynamics in intermediates of molecular photocatalysts-Reference-Cited by-同舟云学术

The electron that breaks the catalyst's back – excited state dynamics in intermediates of molecular photocatalysts

Published:2021 Issue:48 Volume:23 Page:27397-27403
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Müller Carolin¹²^ORCID,Friedländer Ilse²,Bagemihl Benedikt³^ORCID,Rau Sven³^ORCID,Dietzek-Ivanšić Benjamin¹²⁴^ORCID

Affiliation:

1. Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743, Jena, Germany

2. Leibniz Institute of Photonic Technology, Research Department Functional Interfaces, Albert-Einstein-Str. 9, 07745, Jena, Germany

3. Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany

4. Friedrich Schiller University Jena, Center for Energy and Environmental Chemistry Jena (CEEC Jena), Lessingstraße 8, 07743 Jena, Germany

Abstract

Transient absorption spectroelectrochemistry reveals that the singly reduced bridging ligand in a prototype molecular catalyst light driven proton reduction does not allow for electron transfer to the catalytic center – breaking the catalyst's back.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP04498B

Reference39 articles.

1. Electron transfer in a covalent dye–cobalt catalyst assembly – a transient absorption spectroelectrochemistry perspective

2. Cobaloxime-Based Photocatalytic Devices for Hydrogen Production

3. Hydrogen Produced from Hydrohalic Acid Solutions by a Two-Electron Mixed-Valence Photocatalyst