Atom-efficient synthesis of a benchmark electrolyte for magnesium battery applications-Reference-Cited by-同舟云学术

Atom-efficient synthesis of a benchmark electrolyte for magnesium battery applications

Published:2022 Issue:86 Volume:58 Page:12070-12073
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Brown Scott A.¹²,Cussen Serena A.³,Kennard Rhiannon³,Marchesini Sofia²,Pryke Jethro J.³,Rae Annabel¹,Robertson Stuart D.¹^ORCID,Samajdar Rudra N.¹²^ORCID,Wain Andrew J.²^ORCID

Affiliation:

1. WestCHEM, Department of Pure & Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK

2. Department of Electromagnetic & Electrochemical Technologies, National Physical Laboratory, Hampton Road, Teddington, TW11 0LW, UK

3. Department of Materials Science & Engineering, The University of Sheffield, Sheffield, S1 3JD, UK

Abstract

The Mg battery electrolyte complex [Mg2Cl3]+ [AlPh4]− is prepared in high yield with 100% atom economy via a AlCl3/MgPh2 ligand exchange reaction. Spectroscopic studies suggest a simpler solution ionic composition than seen previously whilst maintaining high electrochemical performance.

Funder

Engineering and Physical Sciences Research Council

Faraday Institution

Department for Business, Energy and Industrial Strategy, UK Government

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03290B

Reference24 articles.

1. Corrosion of magnesium electrolytes: chlorides – the culprit

2. Magnesium batteries: Current state of the art, issues and future perspectives

3. Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond

4. Advances in rechargeable Mg batteries

5. Strategies to Enable Reversible Magnesium Electrochemistry: From Electrolytes to Artificial Solid–Electrolyte Interphases

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