Synthesis, structural and toxicological investigations of quarternary phosphonium salts containing the P-bonded bioisosteric CH2F moiety-Reference-Cited by-同舟云学术

Synthesis, structural and toxicological investigations of quarternary phosphonium salts containing the P-bonded bioisosteric CH2F moiety

Published:2020 Issue:33 Volume:44 Page:14306-14315
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Reichel Marco¹²³⁴^ORCID,Unger Cornelia¹²³⁴^ORCID,Dubovnik Sviatlana¹²³⁴,Roidl Andreas¹²³⁴,Kornath Andreas¹²³⁴^ORCID,Karaghiosoff Konstantin¹²³⁴^ORCID

Affiliation:

1. Department Chemie

2. Ludwig-Maximilian-Universität

3. 81377 München

4. Germany

Abstract

Tertiary alkyl, aryl or amino phosphines PR₃ (R = Me, nBu, C₂H₄CN, NEt₂) and the bis[(2-diphenylphosphino)phenyl]ether (POP) were allowed to react with fluoroiodomethane to produce fluoromethyl phosphonium salts in yields between 60–99%.

Funder

Ludwig-Maximilians-Universität München

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ02310H

Reference45 articles.

1. Über Triphenyl‐phosphinmethylene als olefinbildende Reagenzien (II. Mitteil. 1) )

2. Über Triphenyl‐phosphin‐methylene als olefinbildende Reagenzien (I. Mitteil.

3. Alternative synthetic routes to hydrofluoroolefins

4. Synthesis and Properties of the Fluoromethylating Agent (Fluoromethyl)triphenylphosphonium Iodide

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