Optically-pure triptycene-based metallomacrocycles and homochiral self-sorting assisted by ladder formation-Reference-Cited by-同舟云学术

Optically-pure triptycene-based metallomacrocycles and homochiral self-sorting assisted by ladder formation

Published:2023 Issue:58 Volume:59 Page:8989-8992
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Oki Kosuke¹^ORCID,Zheng Wei¹^ORCID,Yashima Eiji¹^ORCID,Ikai Tomoyuki¹²^ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan

2. Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012, Japan

Abstract

Optically-pure and racemic triptycene-derived ladder-type ligands self-assemble with a cis-platinum(ii) complex to form enantiopure and racemic homochiral Pt2L2-type metallomacrocycles, respectively.

Funder

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02259E

Reference30 articles.

1. Triptycene1 (9,10-o-Benzenoanthracene)

2. Synthesis of Trisubstituted Triptycenes and the Optical Resolution of 7-Carboxy-2,5-diacetoxytriptycene

3. Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group

4. Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations

5. Optically active distorted cyclic triptycenes: chiral stationary phases for HPLC

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