Switching between classical/nonclassical crystallization pathways of TS-1 zeolite: implication on titanium distribution and catalysis

Author:

Bai Risheng12ORCID,Song Yue1,Lätsch Lukas3ORCID,Zou Yongcun1,Feng Zhaochi4ORCID,Copéret Christophe3ORCID,Corma Avelino2ORCID,Yu Jihong15ORCID

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

2. Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, Valencia 46022, Spain

3. Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog Weg 1-5/10, 8093 Zürich, Switzerland

4. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

5. International Center of Future Science, Jilin University, Changchun 130012, China

Abstract

This work demonstrates that the dominant crystallization mode of TS-1 zeolite can be switched between the nonclassical route and classical pathway by regulating the kinetic process of crystal nucleation.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

111 Project

European Research Council

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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