Kinetics of the BrO + HO2 reaction over the temperature range T = 246

Kinetics of the BrO + HO2 reaction over the temperature range T = 246–314 K

Published:2017 Issue:34 Volume:19 Page:23345-23356
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ward Michael K. M.¹²³⁴,Rowley David M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University College London

3. London

4. UK

Abstract

The kinetics of the reaction between gas phase BrO and HO₂ radicals, BrO + HO₂ → HOBr + O₂ (1), have been studied over the atmospherically relevant temperature range T = 246–314 K and at ambient pressure, p = 760 ± 20 Torr, using laser flash photolysis coupled with ultraviolet absorption spectroscopy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03854B

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