Nanosecond transient absorption studies of the pH-dependent hydrated electron quenching by HSO3−

Author:

Maza William A.1234ORCID,Breslin Vanessa M.1234ORCID,Plymale Noah T.1234ORCID,DeSario Paul A.5234ORCID,Epshteyn Albert5234ORCID,Owrutsky Jeffrey C.5234ORCID,Pate Bradford B.5234ORCID

Affiliation:

1. National Research Council

2. U.S. Naval Research Laboratory

3. Washington

4. USA

5. Chemistry Division

Abstract

Hydrated electron lifetimes in photodetached sulfite solutions at intermediate pH (5–10) are limited by HSO3 rather than proton (H+) quenching.

Funder

Office of Naval Research

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Reference60 articles.

1. Advanced Reduction Processes: A New Class of Treatment Processes

2. J. Baxendale , Addendum: Redox Potential and Hydration Energy of the Hydrated Electron , Univ. of Manchester , Eng. , 1964

3. Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution

4. Solvated electron; a symposium sponsored by the Division of Physical Chemistry at the 150th Meeting of the American Chemical Society , ed. R. F. Gould , American Chemical Society , Washington, DC , 1965

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