A T-shaped Ni[κ2-(CF2)4–] NHC complex: unusual Csp3–F and M–CFbond functionalization reactions-Reference-Cited by-同舟云学术

A T-shaped Ni[κ2-(CF2)4–] NHC complex: unusual Csp3–F and M–CFbond functionalization reactions

Published:2015 Issue:11 Volume:6 Page:6392-6397
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Andrella Nicholas O.¹²³⁴,Sicard Alexandre J.¹²³⁴,Gorelsky Serge I.¹²³⁴,Korobkov Ilia¹²³⁴,Baker R. Tom¹²³⁴

Affiliation:

1. Department of Chemistry and Centre for Catalysis Research and Innovation(CCRI)

2. University of Ottawa

3. Ottawa

4. ON K1N 6N5 Canada

Abstract

The reactivity of this T-shaped perfluoronickelacyclopentane–NHC complex with Lewis- and Brønsted acids is enhancedvs.4-coordinate variants by its low coordination number.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Canada Research Chairs

Ontario Ministry of Economic Development and Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01886B

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