Comparison between DySc2N@C80 and Dy2ScN@C80 single-molecule magnetic metallofullerenes encapsulated in single-wall carbon nanotubes

Author:

Ito Satoshi1,Nakanishi Ryo1,Katoh Keiichi1ORCID,Breedlove Brian K.1,Sato Tetsu1,Li Zhao-Yang2ORCID,Horii Yoji3ORCID,Wakizaka Masanori1ORCID,Yamashita Masahiro12

Affiliation:

1. Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-Ku, Sendai 980-8578, Japan

2. School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

3. Department of Chemistry, Faculty of Science, Nara Women's University, Nara 6308506, Japan

Abstract

The quantum tunneling mechanism of DySc2N@C80 and Dy2ScN@C80 in single-walled carbon nanotubes was revealed to be tuned in opposite ways.

Funder

Higher Education Discipline Innovation Project

National Natural Science Foundation of China

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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