Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?
Author:
Affiliation:
1. POLYMAT
2. University of the Basque Country UPV/EHU
3. Joxe Mari Korta Center
4. 20018 Donostia-San Sebastián
5. Spain
6. Departamento de Química Inorgánica
7. Universidad del País Vasco UPV/EHU
8. Bilbao
Abstract
Evidence is presented that shows Lewis acid-surfactant complex catalyzed polymerization proceeds via a radical, not a cationic, mechanism.
Funder
Ministerio de Economía y Competitividad
Ekonomiaren Garapen eta Lehiakortasun Saila, Eusko Jaurlaritza
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY00363H
Reference56 articles.
1. Stereoregularity of Poly(vinyl ether)s with a Narrow Molecular Weight Distribution Obtained by the Living Cationic Polymerization
2. Stereoregulation in Cationic Polymerization by Designed Lewis Acids. 1. Highly Isotactic Poly(isobutyl vinyl ether) with Titanium-Based Lewis Acids
3. Stereoregulation in cationic polymerization by designed Lewis acids. II. Effects of alkyl vinyl ether structure
4. Control of Molecular Weight and Tacticity in Stereospecific Living Cationic Polymerization of α-Methylstyrene at 0 °C Using FeCl3 -Based Initiators: Effect of Tacticity on Thermal Properties
5. Isoprene Polymerization with Yttrium Amidinate Catalysts: Switching the Regio- and Stereoselectivity by Addition of AlMe3
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1. Reply to the ‘Comment on “Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?”’ by I. V. Vasilenko, F. Ganachaud and S. V. Kostjuk, Polym. Chem., 2024, 15, DOI: 10.1039/D3PY00661A;Polymer Chemistry;2024
2. Comment on “Lewis acid-surfactant complex catalysed polymerisation in aqueous dispersed media: cationic or radical polymerisation?” by A. Destephen, L. Lezama and N. Ballard, Polym. Chem., 2020, 11, 5757;Polymer Chemistry;2024
3. Water compatible silica supported iron trifluoroacetate and trichloroacetate: as prominent and recyclable Lewis acid catalysts for solvent-free green synthesis of hexahydroquinoline-3-carboxamides;RSC Advances;2023
4. On the limitations of cationic polymerization of vinyl monomers in aqueous dispersed media;Polymer Chemistry;2021
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