Dual photoredox nickel-catalyzed silylation of aryl/heteroaryl bromides using hydrosilanes

Author:

Liu Shuai1,Robert Frédéric1ORCID,Landais Yannick1ORCID

Affiliation:

1. University Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France

Abstract

Silylation of arylbromides with (Me3Si)3SiH via dual photoredox Ni-catalysis enables the preparation of arylsilanes at room temperature under visible-light irradiation.

Funder

China Scholarship Council

Université de Bordeaux

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference39 articles.

1. B. A.Key , Arylsilanes in Science of Synthesis in Houben-Weyl methods of molecular transformations , Compounds of group 15 (As, Sb, Bi) and silicon compounds , ed. I. Fleming , 2002 , vol. 4, p. 685

2. M. A.Brook , Silicon in Organic, Organometallic, and Polymer Chemistry , Wiley , New York , 2000

3. Unusual Electrophilic Substitution in the Aromatic Series via Organosilicon Intermediates

4. Electrophilic Substitution of Organosilicon Compounds- Applications to Organic Synthesis

5. Synthesis of 2,3-Disubstituted Indoles via Palladium-Catalyzed Annulation of Internal Alkynes

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