Bi-functional and mono-component organocatalysts for the ring-opening alternating co-polymerisation of anhydride and epoxide

Author:

Hirschmann Max1ORCID,Zunino Rachele23ORCID,Meninno Sara4ORCID,Falivene Laura4ORCID,Fuoco Tiziana1ORCID

Affiliation:

1. KTH Royal Institute of Technology, Department of Fibre and Polymer Technology, 100 44 Stockholm, Sweden

2. Scuola Superiore Meridionale, 80138 Napoli, Italy

3. University of Naples Federico II, Department of Chemical Sciences, 80126 Napoli, Italy

4. University of Salerno, Department of Chemistry and Biology, 84084 Fisciano, Italy

Abstract

The polyester synthesis from anhydrides and epoxides requires their strictly alternating incorporation achieved by a catalyst that is capable of mediating the reactivity of carboxylate and alcohol chain ends.

Funder

Svenska Forskningsrådet Formas

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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