The site-selectivity and mechanism of Pd-catalyzed C(sp2)–H arylation of simple arenes-Reference-Cited by-同舟云学术

The site-selectivity and mechanism of Pd-catalyzed C(sp2)–H arylation of simple arenes

Published:2021 Issue:1 Volume:12 Page:363-373
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kim Daeun¹²³⁴¹,Choi Geunho¹²³⁴¹,Kim Weonjeong¹⁵⁶⁷⁴,Kim Dongwook⁸⁹³⁴,Kang Youn K.¹⁰¹¹¹²¹³^ORCID,Hong Soon Hyeok¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Korea Advanced Institute of Science and Technology (KAIST)

3. Daejeon 34141

4. Republic of Korea

5. College of Natural Sciences

6. Seoul National University

7. Seoul 08826

8. Center for Catalytic Hydrocarbon Functionalizations

9. Institute for Basic Science (IBS)

10. Department of Chemical Energy Engineering

11. Sangmyung University

12. Seoul 03016

13. Korea

Abstract

The transmetalation step, not the C–H activation step, is suggested as the selectivity-determining step in Pd-catalyzed C–H arylation of simple arenes.

Funder

National Research Foundation of Korea

Korea Institute of Science and Technology Information

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05414C

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