A metal-free one-pot synthesis of benzo[c]chromen-6-ones from 3,4-dichlorocoumarins and butadienes using tandem photo-thermal-photo reactions
Author:
Affiliation:
1. School of Chemistry and Chemical Engineering
2. Guangxi University
3. Nanning
4. China
5. Guangxi Environmental Monitoring Center
6. Nanjing University
7. Nanjing
Abstract
A concise one-pot synthesis of benzo[c]chromen-6-ones from dichlorocoumarins and butadienes has been achieved, using a photo-initiated formal Diels–Alder reaction, with high overall yields.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB01701K
Reference60 articles.
1. Natural Dibenzo-α-Pyrones and Their Bioactivities
2. Benzocoumarins: Isolation, Synthesis, and Biological Activities
3. Natural Dibenzo[b,d]Pyran-6-Ones: Structural Diversity and Biological Activity
4. Multicomponent Synthesis of 6H-Dibenzo[b,d]pyran-6-ones and a Total Synthesis of Cannabinol
5. 6H-Benzo[c]chromen-6-one derivatives as selective ERβ agonists
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