Niobium uptake by a [P8W48O184]40−macrocyclic polyanion
Author:
Affiliation:
1. Nikolaev Institute of Inorganic Chemistry
2. Novosibirsk
3. Russia
4. Novosibirsk State University
5. International Tomography Center
6. Department of Chemistry Oregon State University
7. Oregon 97331-4003
8. USA
Abstract
Incorporation of Nb into the [P8W48O184]40−anionic macrocyclic cavitand leads to formation of new Nb–W POMs. Inclusion of up to five {NbO(H2O)}3+groups was observed. Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and SAXS.
Funder
U.S. Department of Energy
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ01907C
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4. The Wheel-Shaped Cu20 Tungstophosphate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25− Ion
5. Heterogeneous Wheel-Shaped Cu20-Polyoxotungstate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25−Catalyst for Solvent-Free Aerobic Oxidation ofn-Hexadecane
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