The crystal structure of [Mg(dmso)6][BPh4]2and the formation mechanism of the conformer on the basis of conformational analysis

Author:

Sakiyama Hiroshi12345ORCID,Shomura Kaoru12345,Ito Misaki12345,Waki Katsushi12345,Yamasaki Mikio6785

Affiliation:

1. Department of Science

2. Faculty of Science

3. Yamagata University

4. Yamagata 990-8560

5. Japan

6. Application Laboratories

7. Rigaku Corporation

8. Akishima

Abstract

The crystal structure of a new magnesium(ii) complex, [Mg(dmso)6][BPh4]2(1) (dmso: dimethylsulfoxide), was determined, and the reason for the observed structure was clarified by conformational analysis.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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