A 2D rhomboidal system of manganese(ii) [Mn(3-MeC6H4COO)2(H2O)2]n with spin canting: rationalization of the magnetic exchange-Reference-Cited by-同舟云学术

A 2D rhomboidal system of manganese(ii) [Mn(3-MeC6H4COO)2(H2O)2]n with spin canting: rationalization of the magnetic exchange

Published:2018 Issue:11 Volume:47 Page:3717-3724
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Garcia-Cirera Beltzane¹²³⁴⁵^ORCID,Costa Ramon¹²³⁴⁵^ORCID,Moreira Ibério de P. R.⁶³⁴⁵⁷^ORCID,Font-Bardia Mercè⁸⁹³⁴⁵^ORCID,Corbella Montserrat¹²³⁴⁵^ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica

2. Secció Química Inorgànica

3. Universitat de Barcelona

4. 08028-Barcelona

5. Spain

6. Institut de Química Teòrica i Computacional (IQTCUB)

7. Departament de Ciència de Materials i Química Física

8. Unitat de Difracció de RX

9. Centres Científics i Tecnològics de la Universitat de Barcelona (CCiTUB)

Abstract

The 2D rhomboidal net of S = 5/2 spins coupled antiferromagnetically. The tilting of Mn(ii) coordination octahedra induces spin canting at low temperature.

Funder

Ministerio de Economía y Competitividad

European Regional Development Fund

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04380E

Reference39 articles.

1. Structural and Magnetic Properties of Carboxylato-Bridged Manganese(II) Complexes Involving Tetradentate Ligands: Discrete Complex and 1D Polymers. Dependence of J on the Nature of the Carboxylato Bridge