Electrocatalytic reduction of protons to dihydrogen by the cobalt tetraazamacrocyclic complex [Co(N4H)Cl2]+: mechanism and benchmarking of performances-Reference-Cited by-同舟云学术

Electrocatalytic reduction of protons to dihydrogen by the cobalt tetraazamacrocyclic complex [Co(N4H)Cl2]+: mechanism and benchmarking of performances

Published:2022 Issue:1 Volume:6 Page:143-149
ISSN:2398-4902
Container-title:Sustainable Energy & Fuels
language:en
Short-container-title:Sustainable Energy Fuels

Author:

Li Cheng-Bo¹²,Bagnall Andrew J.²³^ORCID,Sun Dongyue²,Rendon Julia²⁴,Koepf Matthieu²^ORCID,Gambarelli Serge⁴,Mouesca Jean-Marie⁴,Chavarot-Kerlidou Murielle²^ORCID,Artero Vincent²^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, The Energy and Catalysis Hub, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

2. Univ. Grenoble Alpes, CNRS, CEA, IRIG, Laboratoire de Chimie et Biologie des Métaux, 17 Rue des Martyrs, F-38054 Grenoble, Cedex, France

3. Ångström Laboratory, Department of Chemistry, Uppsala University, SE75120 Uppsala, Sweden

4. Univ. Grenoble Alpes, CNRS, CEA/IRIG-SyMMES, 17 Rue des Martyrs, F-38054 Grenoble, Cedex, France

Abstract

The mechanism of H2 evolution catalyzed by the [Co(N4H)Cl2]+ complex is elucidated with quantitative determination of the rate-constants for the various protonation steps, and the identification of the aliphatic amine to act as a proton relay.

Funder

FP7 Ideas: European Research Council

Agence Nationale de la Recherche

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SE/D1SE01267C

Reference51 articles.

1. Splitting Water with Cobalt