First evidence of light-induced spin transition in molybdenum(iv)

Author:

Bridonneau N.1234,Long J.1234,Cantin J.-L.5634,von Bardeleben J.5634,Pillet S.7891011,Bendeif E.-E.7891011,Aravena D.12131415ORCID,Ruiz E.12131415,Marvaud V.1234

Affiliation:

1. IPCM-CNRS-UMR-8232

2. UPMC-Univ. Paris 6

3. 75252 Paris Cedex 05

4. France

5. INSP – CNRS UMR-7588

6. UPMC- Univ. Paris 6

7. CRM2

8. UMR CNRS 7036

9. Institut Jean Barriol

10. Université de Lorraine

11. 54506 Vandoeuvre-les-Nancy

12. Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional

13. Universitat de Barcelona

14. E-08028 Barcelona

15. Spain

Abstract

Photo-induced spin transition in a molybdenum–zinc complex has been evidenced: a unique Light-Induced Excited Spin State Trapping Effect (LIESST) on a 4d transition metal ion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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