Control of the cavity size of flexible covalent cages by silver coordination to the peripheral binding sites

Author:

Kocher Lucas12345,Durot Stéphanie12345,Heitz Valérie12345

Affiliation:

1. Laboratoire de Synthèse des Assemblages Moléculaires Multifonctionnels

2. Institut de Chimie de Strasbourg

3. CNRS/UMR 7177

4. Université de Strasbourg

5. 67000 Strasbourg

Abstract

A flexible covalent cage was synthesized thanks to a DABCO-templated CuAAC reaction. Coordination of Ag(i) on the peripheral triazoles locks the conformation of the porphyrin cage.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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