Reductive activation of arenes by potassium metal with potassium salts-Reference-Cited by-同舟云学术

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Reductive activation of arenes by potassium metal with potassium salts

Published:2024 Issue:18 Volume:11 Page:5099-5106
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Nocera Giuseppe¹,Robb Iain¹,Clark Kenneth F.¹^ORCID,McGuire Thomas M.²,Evans Laura²,Chiba Shunsuke³^ORCID,Murphy John A.¹^ORCID

Affiliation:

1. Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK

2. Medicinal Chemistry, Research and Early Development, Oncology R&D, AstraZeneca, Cambridge CB10 1XL, UK

3. School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, Singapore, 637371 Singapore

Abstract

Reaction of benzene with potassium metal + potassium salts leads to formation of biphenyl and dihydrobiphenyls via dimerization of arene radical anions. Sodium salts are much less effective.

Funder

University of Strathclyde

AstraZeneca

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO01027B

Reference39 articles.

1. A Mechanism for Ion Selectivity in Potassium Channels: Computational Studies of Cation-π Interactions

2. Cation–π interactions: computational analyses of the aromatic box motif and the fluorination strategy for experimental evaluation

3. Cation−π Interaction: Its Role and Relevance in Chemistry, Biology, and Material Science

4. Cation−π Interactions in Organic Synthesis

5. Experimental Evidence for Alkali Metal Cation−π Interactions

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