Reactions of the anionic phenylphosphinidene cluster [Os3-(µ-H)(µ-PPh)(CO)10]–and its phenylphosphido isomer [Os3-(µ-PHPh)(CO)10]–with electrophiles. Crystal structures of [Os3H(µ-PMePh)(CO)10] and [{Os3H(PPh)(CO)10}2Hg]-Reference-Cited by-同舟云学术

Reactions of the anionic phenylphosphinidene cluster [Os3-(µ-H)(µ-PPh)(CO)10]–and its phenylphosphido isomer [Os3-(µ-PHPh)(CO)10]–with electrophiles. Crystal structures of [Os3H(µ-PMePh)(CO)10] and [{Os3H(PPh)(CO)10}2Hg]

Published:1991 Issue:5 Volume: Page:1273-1279
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Deeming Antony J.,Doherty Simon,Day Michael W.,Hardcastle Kenneth I.,Minassian Houri

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910001273

Reference13 articles.

1. Syntheses and characterisation of [Os3(CO)11(PRH2)], [(μ2-H)Os3(CO)10(μ2-PRH)] (R = C6H5, p-CH3OC6H4, C6H11) and [(μ2-H)2Os3(CO)9(μ3-PR)] (R = C6H5, C6H11). Interconversion of cluster-bound phosphine and phosphido ligands. Crystal and molecular structures of [(μ2-H)Os3(CO)10(μ2-P(C6H5)H)] and [(μ2-H)2Os3(CO)9(μ3-PC6H5)]

2. The reaction of Ru3(CO)12 and Os3(CO)12 with PH2Ph; the x-ray crystal structures of HRu3(CO)10(PHPh) and H2Ru3(CO)9(PPh)

3. Systematic synthesis and characterisation of phosphido-bridged triosmium carbonyl clusters

4. Cluster activation via cyclometallation. Formation of the cyclometallated triosmium carbonyl cluster [Os3H2(CO)9{P(C6H4)Ph}] and its reactions with phosphorus donor ligands. The X-ray crystal structures of [Os3H2(CO)9{P(C6H4)Ph}] and [Os3H(CO)9{P(OMe)3}(PPh2)]

5. Reactions of the cyclometallated triosmium cluster [Os3H2(CO)9{P(C6H4)Ph}] with brøsnsted acids and dihydrogen: synthesis and X-ray crystal structure of [Os3H2(CF3CO2)(CO)9(µ-PPh2)]

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