Heterobinuclear IrRh, RuRh and Rulr complexes with pyrazolate bridging ligands: reactivity towards chelating diphosphines; crystal structure of [(C5Me5)Ir(µ-pz)2(µ-CO)-Ir(CO)(dppen)]BPh4·0.5MeOH [pz = pyrazolate, dppen =cis-1,2-bis(diphenylphosphino)ethylene]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910002811
Reference35 articles.
1. The Coordination Chemistry of Pyrazole-Derived Ligands
2. Mixed-valence pyrazolate rhodium complexes. Molecular structure of [(C5Me5)ClRhCl(pz)Rh(tfb)]·CH2Cl2(Hpz = pyrazole; tbf = tetrafluorobenzobarrelene)
3. Heterobinuclear pyrazolate-bridged ruthenium(II)rhodium(I), iridium(III)-rhodium(I), and rhodium(III)iridium(I) complexes. Crystal structure of [(p-cymene)Ru(μ-Cl)2(μ-pz)Rh(tetrafluorobenzo[5.6]bicyclo[2.2.2]octan-2,5,7-triene)]
4. Synthesis and characterization of the alkoxycarbonyl complexes [(C5Me5)M(µ-pz)(µ-I)2Rhl(CO2R)(CO)](M = Rh, R = Me or Et; M = Ir, R = Me; pz = pyrazolate). Molecular structure of [(C5Me5)Ir(µ-pz)(µ-I)2Rhl(CO2Me)(CO)]
5. F. A. Cotton and G.Wilkinson, Advanced Inorganic Chemistry, 5th edn., Wiley, New York, 1988, p. 1028.
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