Surfactant-free emulsion polymerization of vinylidene fluoride mediated by RAFT/MADIX reactive poly(ethylene glycol) polymer chains

Author:

Fuentes-Exposito Mathieu1ORCID,Norsic Sébastien1,Février Thibaut1,Dugas Pierre-Yves1,Boutti Salima2,Devisme Samuel3,Bonnet Anthony2,D'Agosto Franck1ORCID,Lansalot Muriel1ORCID

Affiliation:

1. Univ Lyon, Université Claude Bernard Lyon 1, CPE Lyon, CNRS, UMR 5128, Catalysis, Polymerization, Processes and Materials (CP2M), 43 Bd du 11 Novembre 1918, 69616 Villeurbanne, France

2. ARKEMA, Centre de Recherche Rhône-Alpes (CRRA), Rue Henri Moissan - CS 42063, 69491 Pierre-Bénite Cedex, France

3. ARKEMA, Centre de recherche, développement, applications et technique de l'ouest (Cerdato), 13 route de Launay, 27470 Serquigny, France

Abstract

Vinylidene fluoride (VDF) emulsion polymerization is conducted in the presence of xanthate-end functionalized poly(ethylene glycol)s leading to stable PVDF latexes.

Funder

Arkema

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference76 articles.

1. From Vinylidene Fluoride (VDF) to the Applications of VDF-Containing Polymers and Copolymers: Recent Developments and Future Trends

2. J. T.Goldbach , R.Amin-Sanayei , W.He , J.Henry , W.Kosar , A.Lefebvre , G.O'Brien , D.Vaessen , K.Wood and S.Zerafati , in Fluorinated Polymers: Volume 2: Applications , The Royal Society of Chemistry , 2017 , vol. 2 , pp. 127–157

3. The Promising Future of Fluoropolymers

4. Reaction engineering of the emulsion homopolymerization of vinylidene fluoride: Progress and challenges

5. Kinetics of the Emulsion Polymerization of Vinylidene Fluoride and Hexafluoropropylene

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