Combined heterogeneous bio- and chemo-catalysis for dynamic kinetic resolution of (rac)-benzoin-Reference-Cited by-同舟云学术

Combined heterogeneous bio- and chemo-catalysis for dynamic kinetic resolution of (rac)-benzoin

Published:2014 Issue:85 Volume:4 Page:45495-45503
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Nieguth R.¹²³⁴,ten Dam J.⁵⁶⁷⁸⁹,Petrenz A.¹⁰¹¹¹²¹³,Ramanathan A.⁵⁶⁷⁸⁹,Hanefeld U.⁵⁶⁷⁸⁹,Ansorge-Schumacher M. B.¹²³⁴¹⁰

Affiliation:

1. Lehrstuhl für Technische Chemie/Enzymtechnologie

2. Institut für Chemie

3. Technische Universität Berlin

4. 10623 Berlin, Germany

5. Gebouw voor Scheikunde

6. Biokatalyse

7. Afdeling Biotechnologie

8. Technische Universiteit Delft

9. Delft, The Netherlands

10. Professur für Molekulare Biotechnologie

11. Institut für Mikrobiologie

12. Technische Universität Dresden

13. 01062 Dresden, Germany

Abstract

A highly efficient system for the enantiopure synthesis of benzoin was developed. The reaction system employed lipase TL from Pseudomonas stutzeri immobilized on Accurel MP1001 (Acc-LipTL) and Zr-TUD-1 (Si/Zr = 25), an acidic mesoporous silicate, for dynamic kinetic resolution of racemic benzoin in one pot.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA06751G

Reference52 articles.

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3. Chiral Cobalt-Catalyzed Enantiomer-Differentiating Oxidation of Racemic Benzoins by Using Molecular Oxygen as Stoichiometric Oxidant

4. Chiral iron complex catalyzed enantioselective oxidation of racemic benzoins

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