Charge transfer reactions between gas-phase hydrated electrons, molecular oxygen and carbon dioxide at temperatures of 80

Charge transfer reactions between gas-phase hydrated electrons, molecular oxygen and carbon dioxide at temperatures of 80–300 K

Published:2016 Issue:34 Volume:18 Page:23528-23537
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Akhgarnusch Amou¹²³⁴⁵,Tang Wai Kit⁶⁷⁸⁹¹⁰,Zhang Han⁶⁷⁸⁹¹⁰,Siu Chi-Kit⁶⁷⁸⁹¹⁰,Beyer Martin K.¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Physikalische Chemie

2. Christian-Albrechts-Universität zu Kiel

3. 24098 Kiel

4. Germany

5. Institut für Ionenphysik und Angewandte Physik

6. Department of Biology and Chemistry

7. City University of Hong Kong

8. 83 Tat Chee Avenue

9. Hong Kong SAR

10. P. R. China

Abstract

With a combination of mass spectrometry and quantum chemistry, we derive hydration enthalpies for CO₂˙⁻ and O₂˙⁻ and show that the charge transfer from CO₂˙⁻ to O₂ proceeds via a CO₄˙⁻ intermediate.

Funder

City University of Hong Kong

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03324E

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