Redox-induced umpolung of transition metal carbenes
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of Notre Dame
3. Notre Dame
4. USA
Abstract
An unprecedented umpolung of a nucleophilic palladium carbene complex was realized by successive one-electron oxidations to generate a cationic carbene complex, which shows electrophilic behavior toward nucleophiles resulting from a polarity inversion of the Pd–Ccarbene bond.
Funder
American Chemical Society Petroleum Research Fund
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02859K
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