New Pt→M (M = Ag or Tl) complexes based on anionic cyclometalated Pt(ii) complexes-Reference-Cited by-同舟云学术

New Pt→M (M = Ag or Tl) complexes based on anionic cyclometalated Pt(ii) complexes

Published:2019 Issue:10 Volume:48 Page:3270-3283
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Campillo David¹²³⁴⁵^ORCID,Belío Úrsula¹²³⁴⁵,Martín Antonio¹²³⁴⁵^ORCID

Affiliation:

1. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

2. Departamento de Química Inorgánica

3. Universidad de Zaragoza – CSIC

4. 50009 Zaragoza

5. Spain

Abstract

Anionic cyclometalated complexes (NBu₄)[Pt(CNC)X] (X = Cl, CN, or S-2py) react with Ag(i) and Tl(i) salts to give complexes containing Pt→M donor–acceptor intermetallic bonds. These complexes show a wide range of structural dispositions depending on M and the bridging characteristics of the ligand X.

Funder

Ministerio de Economía y Competitividad

Gobierno de Aragón

European Social Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00121B

Reference78 articles.

1. Intramolecular d10–d10 interactions in heterometallic clusters of the transition metals