The sensitive determination of Ag, Pb and Tl as well as reduction of spectral interferences in a hanging drop cathode atmospheric pressure glow discharge excitation microsource equipped with a Dove prism system

Author:

Swiderski Krzysztof1ORCID,Greda Krzysztof1ORCID,Pohl Pawel1ORCID,Jamroz Piotr1ORCID

Affiliation:

1. Department of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wroclaw University of Science and Technology, Wyb. Wyspianskiego 27, 50-370 Wroclaw, Poland

Abstract

A hanging drop cathode APGD-OES system coupled with Dove prism is reported. The reduction of spectral interferences and enhancement of the Ag, Pb and Tl atomic emission lines was the most spectacular and resulted in improved LODs of these elements.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Spectroscopy,Analytical Chemistry

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