Water and catalytic isomerization of linear allylic alcohols by [RuCp(H2O-κO)(PTA)2]+(PTA = 1,3,5-triaza-7-phosphaadamantane)-Reference-Cited by-同舟云学术

Water and catalytic isomerization of linear allylic alcohols by [RuCp(H2O-κO)(PTA)2]+(PTA = 1,3,5-triaza-7-phosphaadamantane)

Published:2017 Issue:18 Volume:46 Page:5864-5871
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Scalambra Franco¹²³⁴⁵,Serrano-Ruiz Manuel¹²³⁴⁵,Romerosa Antonio¹²³⁴⁵^ORCID

Affiliation:

1. Área de Química Inorgánica-CIESOL

2. Facultad de Ciencias

3. Universidad de Almería

4. Almería

5. Spain

Abstract

The water soluble complex [RuCp(H₂O-κO)(PTA)₂]⁺showed to be an excellent catalyst for the isomerization of allylic alcohols from 3-buten-2-ol to 1-octen-3-ol in water, which was mandatory for obtaining the best conversion.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Agencia de Innovación y Desarrollo de Andalucía

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04262G

Reference52 articles.

1. Homogeneously catalysed isomerisation of allylic alcohols to carbonyl compounds

2. Transposition of Allylic Alcohols into Carbonyl Compounds Mediated by Transition Metal Complexes

3. Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes

4. Iridium-Catalyzed Selective Isomerization of Primary Allylic Alcohols

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