Highly efficient synergistic CO2 conversion with epoxide using copper polyhedron-based MOFs with Lewis acid and base sites

Author:

Gu Jiaming12345,Sun Xiaodong67289ORCID,Liu Xinyao12345ORCID,Yuan Yang12345,Shan Hongyan12345,Liu Yunling12345ORCID

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

2. College of Chemistry

3. Jilin University

4. Changchun 130012

5. P. R. China

6. Institute of Clean Energy Chemistry

7. Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials

8. Liaoning University

9. Shenyang 110036

Abstract

The catalytic performances and effect of LASs and LBSs of four isomorphous Cu-PMOFs in CO2 cycloaddition reaction were systematically studied. JLU-Liu21 exhibited significant catalytic efficiency, remarkable recyclability and catalytic stability.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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