Nickel-catalyzed C–H alkylation of indoles with unactivated alkyl chlorides: evidence of a Ni(i)/Ni(iii) pathway-Reference-Cited by-同舟云学术

Nickel-catalyzed C–H alkylation of indoles with unactivated alkyl chlorides: evidence of a Ni(i)/Ni(iii) pathway

Published:2019 Issue:41 Volume:10 Page:9493-9500
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Pandey Dilip K.¹²³⁴⁵,Ankade Shidheshwar B.¹²³⁴⁵,Ali Abad¹²³⁴⁵,Vinod C. P.⁶⁷⁸⁵^ORCID,Punji Benudhar¹²³⁴⁵^ORCID

Affiliation:

1. Organometallic Synthesis and Catalysis Group

2. Chemical Engineering Division

3. CSIR–National Chemical Laboratory (CSIR–NCL)

4. Pune 411 008

5. India

6. Catalysis Division

7. CSIR–NCL

8. Pune

Abstract

A mild and efficient nickel-catalyzed method for the chemo and regioselective coupling of unactivated alkyl chlorides with the C–H bond of indoles and pyrroles at 60 °C is described.

Funder

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01446B

Reference75 articles.

1. The Combinatorial Synthesis of Bicyclic Privileged Structures or Privileged Substructures

2. Reserpine: A Challenge for Total Synthesis of Natural Products

3. Variolins and Related Alkaloids

4. Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

5. Controlling bacterial behavior with indole-containing natural products and derivatives

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