π-Topology and spin alignment in the photo-excited states of phenylanthracene-t-butylnitroxide radicals

Author:

Teki Yoshio12345,Miyamoto Sadaharu12345,Koide Kentaro12345

Affiliation:

1. Division of Molecular Material Science

2. Graduate School of Science

3. Osaka City University

4. Osaka 558-8585

5. Japan

Abstract

We have studied the relationship between the π-topology and the photo-excited high-spin states of π-conjugated spin systems, 9-anthracen-(3-phenyl-t-butylnitroxide) radical (1m) and 9-anthracen-(4-phenyl-t-butylnitroxide) radical (1p) systems, by time-resolved ESR and transient absorption spectroscopies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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