Water-assisted ketonization of methyl palmitate to palmitone over metal incorporated TiO2 catalysts

Author:

Pittayatornkul Jetsadagorn1,Maluangnont Tosapol2ORCID,Jongpatiwut Siriporn3,Praserthdam Piyasan4ORCID,Ogawa Makoto5,Sooknoi Tawan16ORCID

Affiliation:

1. Department of Chemistry, School of Science, King Mongkut's Institute of Technology Ladkrabang, Bangkok, 10520, Thailand

2. College of Materials Innovation and Technology, King Mongkut's Institute of Technology Ladkrabang, Bangkok, 10520, Thailand

3. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330, Thailand

4. Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand

5. School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, 555 Moo 1 Payupnai, Wangchan, Rayong 21210, Thailand

6. Catalytic Chemistry Research Unit, School of Science, King Mongkut's Institute of Technology Ladkrabang, Bangkok, 10520, Thailand

Abstract

Over 0.5Pd/TiO2, water promotes hydrolysis of methyl palmitate to palmitic acid that undergoes ketonization to palmitone. Pd dissociates H2 and facilitates H2-spillover for the generation and recovery of Lewis Ti3+ active sites.

Funder

National Research Council of Thailand

King Mongkut's Institute of Technology Ladkrabang

Publisher

Royal Society of Chemistry (RSC)

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