Synthesis of phosphorescent syn, anti-isomeric clamshell platinum(ii) dimers for OLED applications

Author:

Yao Haibo12,Qiao Lige1,Yuan Lequn1,Luan Xueyin1,Shen Yunjun1ORCID,Zhang Yuzhen1ORCID,Zhou Liang3ORCID,Bian Hedong1ORCID

Affiliation:

1. Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, Guangxi, China

2. Engineering Research Center for Industrial Wastewater Treatment and Reuse of Shandong Province, School of Chemical Engineering and Safety, Shandong University of Aeronautics, Binzhou 256603, Shandong, China

3. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Abstract

Six clamshell diplatinum(ii) complexes with a formula of [Pt(TBPCH)(N^N)]2 bearing both a carbazole-pyrimidine chelate and a N^N bridge, (TBPCH2 = 3,6-di-tert-butyl-9-(pyrimidin-2-yl)-9H-carbazole), have been prepared by utilizing TBPCH2 (C^N) as the primary ligand and N^N as the bridging ligand.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangxi Province

Publisher

Royal Society of Chemistry (RSC)

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