Bioinspired redox-coupled conversion reaction in FeOOH-acetate hybrid nanoplatelets for Na ion battery

Author:

Park Bum Chul12,Cho Jiung3,Zhang Jiliang12,Amedzo-Adore Mawuse4,Lee Dae Beom12,Kim Sung-Chul5ORCID,Bae Jong Seong6,Uhm Young Rang7,Kim Sang-Ok8ORCID,Koo Jehyoung3,Kang Yong-Mook129ORCID,Kim Young Keun12ORCID

Affiliation:

1. Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea

2. Brain Korea Center for Smart Materials and Devices, Korea University, Seoul 02841, Republic of Korea

3. Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Republic of Korea

4. Department of Energy and Materials Engineering, Dongguk University, Seoul 04620, Republic of Korea

5. Advanced Analysis Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea

6. Busan Center, Korea Basic Science Institute, Busan 46742, Republic of Korea

7. Nuclear Materials Research Division, Korea Atomic Energy Research Institute (KAERI), Daejeon 34057, Republic of Korea

8. Energy Storage Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea

9. KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul 02841, Republic of Korea

Abstract

FeOOH complexed with acetate exploits the stepwise intercalation/conversion and biotic Fe redox, enabling a highly reversible conversion reaction. FeOOH reduction coupled with acetate oxidation after Na ion intercalation gives a solid framework for stable Na ion storage.

Funder

National Research Foundation of Korea

KU-KIST Graduate School of Converging Science and Technology

Ministry of Science and ICT, South Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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