Six-coordinate high-spin iron(ii) complexes with bidentate PN ligands based on 2-aminopyridine – new Fe(ii) spin crossover systems

Author:

Holzhacker Christian123,Calhorda Maria José4567,Gil Adrià4567,Carvalho Maria Deus4567,Ferreira Liliana P.85679,Stöger Berthold1023,Mereiter Kurt1023,Weil Matthias1023,Müller Danny123,Weinberger Peter123,Pittenauer Ernst1023,Allmaier Günter1023,Kirchner Karl123

Affiliation:

1. Institute of Applied Synthetic Chemistry

2. Vienna University of Technology

3. A-1060 Vienna, Austria

4. Centro de Química e Bioquímica/DQB

5. Faculdade de Ciências

6. Universidade de Lisboa

7. 1749-016 Lisboa, Portugal

8. Centro de Física da Matéria Condensada/DF

9. Departamento Física

10. Institute of Chemical Technologies and Analytics

Abstract

Octahedral 18e iron(ii) complexes of the type [Fe(PNR-Ph)2X2] are prepared and characterized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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